Any tooth surface can develop a cavity, but some surfaces are more prone, including newly erupted teeth due to immature enamel and teeth with developmental defects.
The cells that manufacture enamel are very sensitive to systemic insults. Disruption in the enamel production during tooth development will result in a defect which may be microscopic or macroscopic.
Oliveira AF, Chaves AM, Rosenblatt A. The influence of enamel defects on the development of early childhood caries in a population with low socioeconomic status: a longitudinal study. Caries Res. 2006;40(4):296-302.
Targino AG, Rosenblatt A, Oliveira AF, Chaves AM, Santos VE. The relationship of enamel defects and caries: a cohort study. Oral Dis. 2011 May;17(4):420-6.
Jacobsen PE, Haubek D, Henriksen TB, et al. Developmental enamel defects in children born preterm: a systematic review. Eur J Oral Sci. 2014; 122(1):7-14.